Saturday, September 16, 2017

Calcite and some of its interesting properties


The mineral calcite consists of calcium carbonate CaCO3. It is a very common mineral that makes up limestone. Beginning students in geology labs quickly learn that calcite can be easily identified because it fizzes in weak hydrochloric acid.

Also, if the crystal of calcite is clear (transparent), any writing underneath of it is "doubled" when viewed. This effect is shown in the first two images below. The first image is of  a small, clear crystal, about 3 cm across. It is sitting on a white piece of paper, with the letter "X" written on it. Light is refracted through the crystal and produces the "doubling" effect (called double refraction). Single perfect crystals like this one, have what is known as the rhombohedron shape (a six-sided prism).  



The second image is of a longer (7.5 cm) clear rhombohedron crystal, sitting on a white piece of paper with the word "calcite" written on it. 



There are also other colored varieties of calcite, as shown in the following "color wheel." For scale, the green crystal is 4 cm length.


These varieties, which I had available, show a range in color of calcite, from orange, red-orange, red, yellow-brown, clear, light yellow, blue, green, and (in the center) honey color. There are other intermediate colors. Impurities in the crystals cause the different colors.

The "black looking" crystal at the bottom of this "color wheel" is actually a clear crystal, and the black background used in making the photo shows through this clear crystal.

A last picture, shown below, is of a stalactite of calcite from the ceiling of a cave. The calcite crystals formed by dissolving out of underground water and dripping into an open space (a cave). The structure is 5 cm in height.



Saturday, September 2, 2017

Eocene oyster Cubitostrea sellaeformis

If you have been a reading my posts for the last three years, you will know that I have a strong interest in fossil oysters. I return to them with this post, which concerns the middle Eocene (about 45 million years old) oyster Cubitostrea sellaeformis (Conrad, 1832), known from Alabama, Georgia, Louisiana, North Carolina, South Carolina, Texas, and Mexico. This oyster has a strongly arched, large-size shell, and, if you look at the digital image below, you can see the U-shaped "line" that separates the two valves shown in side view.



I collected this complete specimen in 1989, when I visited southern Alabama. The specimen is from the upper part of the Lisbon Formation. The lower valve (left valve), which is thick and heavy,  sat on the bottom of the shallow ocean. The upper valve (right valve), which is lid-like is smaller and comparatively lighter.


This is the exterior of the lower valve, which is 14 cm long.


This is the exterior of the upper valve, which is 13 cm long. The "ears" (auricles) are part of the other valve.



These are the interiors of both valves, with the lower valve on the left side of the picture, and the right valve on the right side of the picture. If you look closely, you can see the muscle scar, especially on the upper middle part of the lower valve.

If you are wondering what caused the peculiar shape of this species, "join the crowd." No one has determined the answer with any degree of certainty. Its large size allowed it to live in shallow-marine waters in front of barrier beaches (unlike brackish-water, lagoon-living smaller oysters). It is possible that individuals crowded together and took on unusual shapes so as to withstand agitated-water conditions. The "ears" possibly served as stabilizing "anchors" for the lower valve.

Saturday, August 19, 2017

Two Late Cretaceous species of the bivalve Pterotrigonia

In some cases, recognition of two species of the same genus can be problematic. In the examples shown here, however, the recognition  is straightforward. The species are of a shallow-marine bivalve (clam) of Late Cretaceous age from the west coast of North America. These species lived as burrowers in subtidal shelfal depths.


Pterotrigonia klamathonia, 4.5 cm length, Santa Ana Mountains,
Turonian age, Orange County, southern California.

Pterotrigonia klamathonia (Anderson, 1958), which is of Turonian age, is characterized by its closely spaced radial ribs, 20 to 25 in number.

Pterotrigonia evansana, 4.5 cm length, Campanian age,
Simi Hills, Ventura County, southern California.
Pterotrigonia evansana (Meek, 1858) is geologically younger and is of Coniacian through Campanian age (see time table below). This species is characterized by its widely spaced radial ribs, commonly 10 or so in number.


Genus Pterotrigonia, which is the state fossil of Tennessee, is extinct. It belongs to the family Megatrigoniidae, whose geologic time range is latest Jurassic through the end of the Cretaceous. The family was very widespread in the world during the Cretaceous.

Saturday, August 5, 2017

"Desert Roses"

“Desert roses” are clusters of crystals of baryte or gypsum containing inclusions of sand. “Baryte” is the new official spelling of the mineral barite. “Desert roses” are also called “sand roses,” “rose rock,” “gypsum rose,” and “gypsum rosettes.” The clusters can be spherical shaped, irregular, or columnar shaped. They are commonly red or reddish brown.


These three pictures shown baryte "desert roses," and the largest one shown above is 2 inches in diameter. They feel heavy to the touch because of the element barium.


"Desert roses" form as evaporites when shallow waters (marine lagoons or lakes) rich in sulfates containing the elements barium or calcite precipitate out of solution. 

“Desert roses” are not that common although it seems that every collector I know has one or two. They are found in Kansas, Oklahoma, Arizona, California, Egypt, and a few other places in the world where lake beds have dried up and become evaporites. They can be of any geologic age (e.g., Permian [250 million years old] or Plio-Pleistocene [less than about 3 million years old]).


Some of the most famous and largest (up to 39 inches tall and weighing as much as 1,000 pounds) specimens of “desert roses” are from the Permian-age (about 275 million years old) Garber Sandstone in Oklahoma. In fact, in 1968, “desert roses” became known as the official state rock of Oklahoma.


Like the one shown above (1.5 inches long), not all clusters of baryte contain inclusions of sand nor do they necessarily have to form as evaporites. 




Saturday, July 22, 2017

Sodalite and lapis lazuli


Sodalite can be confused with the rarer and more expensive lapis lazuli (shortened or casual version of this word is lapis), which is also blue. This post deals with how to tell them apart.

Sodalite is a mineral. It is named for its sodium content, consists of the elements sodium, aluminum, silicon, oxygen, and chlorine. It belongs to a group of minerals called the feldspathoids, which resemble feldspars but have a different crystalline structure, a much lower silica content (i.e., feldspathoids are never found in rocks congaing primary quartz), and contain sulfur or chlorine. Sodalite is an ornamental gemstone and is commonly used in jewelry or in making bookends, etc. It is best known for its blue color, but it can also be gray, yellow, green, and commonly mottled in color. It commonly has white veining. It rarely has inclusions of pyrite, and it is not opaque (thus light can transmit through its edges).
Bookends made of sodalite. They are 13 cm hight.

Other side of the bookends shown above.
A small piece of sodalite (5 cm maximum dimension) with a polished surface.
Sodalite has poor cleavage, therefore, it is useful for making carvings of animals. This mineral is commonly found as vein fillings in plutonic igneous rocks (such as nepheline syenites). Associated minerals are microcline, albite, calcite, fluorite, and baryte (barite). It is found in Canada (Ontario, Quebec, and British Columbia), as well as in Maine and Arkansas. 

Sodalite is a "poor man's lapis lazuli."

Lapis lazuli is a metamorphic rock. The most obvious and important  component of this rock is the mineral lazurite, a feldspathoid silicate mineral consisting of sodium, calcium, aluminum, silicon, oxygen, chlorine, and sulfur. It is the presence of sulfur that gives lazurite its intense deep blue color. Most lazurite also contains the minerals calcite (white), sodalite (blue) and sparkling pyrite, as well as small amounts of mica, hornblende, etc.  

The gem form of Lapis lazuli has been prized since antiquity for its deep-blue color. This rock has been mined for thousands of years in Afghanistan and Pakistan (note: "lapis" is an Arabic word). It is opaque, thus light does not transmit through its edges. Pyrite is commonly present, but in minor amounts.
A small piece of polished gem-quality lapis lazuli (3 cm maximum
 dimension). Notice the flecks of pyrite.

Flip side of the lapis lazuli shown above. Notice the vein of calcite
with some pyrite veinlets.
Lapis lazuli takes an excellent polish and can be made into jewelry, carvings, mosaics, ornaments, small statues, and vases. 


Sunday, July 9, 2017

Amazonite

Amazonite: A case study in how a geologist thinks

Amazonite is a bright-green variety of the mineral microcline feldspar. Amazonite occurs in quartz-rich granitic rocks, especially coarse-grained granites called pegmatites, like the one shown here.
This sample is probably from the Pikes Peak region in Colorado, where some of the highest quality specimens are found. The name “amazonite” is derived from the Amazon River because early collectors believed (erroneously) they had found amazonite there.

Amazonite (10 cm maximum dimension) in pegmatite granite. Bright green = microcline; grayish and whitish (both can be somewhat transparent = quartz; white = microcline; black = biotite). The underside of this rock is cuneiform graphic granite (see previous post).
This post presents an opportunity to point out the "visual clues" a geologist would use to explain how this rock formed. 

The rock consists of interlocking large crystals of several minerals. The interlocking of the crystals indicates that they formed from magma (molten material), and the large size of the crystals means that they cooled very slowly. The rock, therefore, is a plutonic igneous rock that cooled very slowly underground. The word "plutonic" is derived from the name of the Roman god, Pluto, who lived underground.

The presence of quartz means the rock formed late in the fractional crystallization sequence. As the magma cooled, a certain sequence of  minerals form, and the chemistry of the remaining melt changes.
This sequence is elegantly summarized by what is known as the Bowen Reaction Series (see diagram at the end of this post).


The presence of lamellae of different colors (green and white) in the overall bright green crystals means that there was exsolution of two minerals: white is albite, and green is microcline. These two minerals crystallized together when the remaining magma melt was rich in potassium, with a lesser amount of sodium. These lamellae form what is known as perthitic texture, which is common to the alkali feldspars (late-forming minerals rich in potassium). 


Amazonite (3.8 cm thick), showing exsolution lamellae of albite (white color).

 The bright green color of amazonite was a mystery to science until detailed studies showed that its color is a result of natural radiation of microcline containing a relatively high level of lead and water in the crystalline structure.  




This poster depicts a poster I made that shows the progressive sequence of fractional crystallization of the Bowen's Reaction Series. It was not made with the intention of showing it online. This explains why the the writing on the poster is somewhat hard to read. Although the dark minerals do not show up well, the poster conveys the concept of the sequence of minerals that form in  an ideal (in a chemical composition sense) magma as it cools. 

Monday, June 26, 2017

Tourmaline-bearing granite

A granite is very distinctive looking if it contains "clusters, spots, clots, or patches" of jet-black tourmaline crystals surrounded by white feldspar crystals.  Such a white-colored granite is   leucocratic (i.e., dark-colored minerals absent or, in this case, concentrated).  Black tourmaline is called schorl, and it is black because of its iron content.  Tourmaline, which is a boron-silicate mineral, is commonly found in pegmatites.  In my previous post, I discussed that pegmatites are associated with the late stages of the cooling history of granite-producing magmas.

A single large crystal (4.75 cm tall = 1.87 in.) of schorl is shown in the following image.  The overall shape of the crystal is triangular  and has striations on all of its sides. The provenance of this crystal is unknown.



Three small boulders (all about 13 inches maximum length) of tourmaline granite are shown below.  A 3/4 of an inch in diameter penny (United States) is used for scale. The "clusters" of tourmaline can be as large as 8 cm across.  The provenance (original location) of this granite is not known to me, but the boulders occurred as rock debris emanating from a man-made dam built in a stream bed in northern Los Angeles County.  I was not sure about the identification of the black mineral in these rocks, so I asked my friend and colleague, Dr. Larry Collins, who is a professor emeritus of geology to take a look at the mineral. He is an expert in mineralogy and petrology, and he recognized the mineral as tourmaline.








In this image, the tourmaline crystals are more spread out, with feldspar and quartz in between. 


This image is a closeup showing a divergent fibrous aggregate of acicular (needle-like) tourmaline crystals, which are concentrated in the upper half of the image. The tourmaline in the lower half of the image is blocky. The entire field of view is about 1 cm in height.

The image below shows a small of piece of a tourmaline-bearing granite (5.5 cm width) from a pegmatite at the Stewart Mine near Pala, San Diego County, Southern California. These crystals of schorl are somewhat massive (structureless).